(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide

Garden, S.J. and Pinto, A.C. and da Cunha, F.R. and Fontes, S.P. and Lima, A.S. and Tiekink, E.R.T. (2010) (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide. Acta Crystallographica Section E: Structure Reports Online, 66 (6). O1436-U1657. ISSN 1600-5368

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Abstract

The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot center dot N hydrogen bond occurs. Linear supramolecular chains along the b axis mediated by O-H center dot center dot center dot O hydrogen-bonding interactions feature in the crystal structure. These chains are also stabilized by weak C-H center dot center dot center dot N contacts.

Item Type: Article
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 16 Apr 2015 08:27
Last Modified: 31 Jan 2019 04:09
URI: http://eprints.um.edu.my/id/eprint/13272

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