Tang, E. and Dai, Yu-Mei and Chen, Y. and Lang, Jian-Ping and Yao, Yuan-Gen and Weng, Ng-Seik (2010) Encapsulation of unique anionic carboxylic acid/water cluster chains into channels of a three-dimensional cationic framework. Inorganic Chemistry Communications, 13 (7). pp. 887-890.
Full text not available from this repository.Abstract
The hydrothermal reactions of CuCl with 1,3-bis(4-pyridyl)propane (bpp), 1,3-benzenedicarboxylic acid (1,3-H(2)bdc), and KOH in water afforded {[Cu(8)Cl(4)(bpp)(8)][(1,3-Hbdc)(4)(H(2)O)(9.5)]}(n) (1). Single-crystal X-ray diffraction revealed that 1 has anionic [(1,3-Hbdc)(4)(H(2)O)(9.5)](n)(4n-) water cluster chains that are encapsulated into the 1D channels of a 3-D [Cu(8)Cl(4)(bpp)(8)](n)(4n+) cationic framework. The thermal and luminescent properties of 1 in the solid state were also investigated. (C) 2010 Elsevier BM. All rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Solvothermal synthesis; 1,3-Bis(4-pyridyl)propane; 1,3-Benzenedicarboxylic acid; Anionic water cluster chain; 3D cationic framework |
| Subjects: | R Medicine |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 25 Mar 2015 02:41 |
| Last Modified: | 25 Mar 2015 02:41 |
| URI: | http://eprints.um.edu.my/id/eprint/13109 |
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