3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one

Zukerman-Schpector, J. and De Simone, C.A. and Olivato, P.R. and Cerqueira, C.R. and Santos, J.M.M. and Tiekink, E.R.T. (2010) 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one. Acta Crystallographica Section E: Structure Reports Online, 66 (7). O1863-U1080. ISSN 1600-5368,

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Abstract

The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)degrees]. In the crystal, C-H center dot center dot center dot O interactions link the molecules into [010] supramolecular chains with a helical topology. C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also present.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 12 Feb 2015 03:23
Last Modified: 30 Jan 2019 08:16
URI: http://eprints.um.edu.my/id/eprint/12728

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