(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)

Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M1021-U1469. ISSN 1600-5368,

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Abstract

The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O-H...N hydrogen bond with an N-atom acceptor site.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 05 Feb 2015 01:59
Last Modified: 30 Jan 2019 08:26
URI: http://eprints.um.edu.my/id/eprint/12562

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