Kingianin A: A new natural pentacyclic compound from Endiandra kingiana

Leverrier, A. and Dau, M.E.T.H. and Retailleau, P. and Awang, Khalijah and Gueritte, F. and Litaudon, M. (2010) Kingianin A: A new natural pentacyclic compound from Endiandra kingiana. Organic Letters, 12 (16). pp. 3638-3641.

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Abstract

A new natural pentacyclic compound, named kingianin A, was isolated as a racemic mixture from the barks of Endiandra kingiana (Lauraceae). Its structure was elucidated by comprehensive analysis of NMR spectroscopic data, X-ray crystallography, and ECD calculations. The pentacyclic skeleton may be formed by a Diels-Alder reaction between two monomers having a bicyclo[4.2.0]octadiene backbone formed by a stereospecific electrocyclization of a linear compound of polyketide origin.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:16
Last Modified: 01 Mar 2019 08:59
URI: http://eprints.um.edu.my/id/eprint/12551

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