Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]

Mohammadnezhad, G. and Ghanbarpour, A.R. and Amini, M.M. and Ng, S.W. (2010) Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1120-U735. ISSN 1600-5368,

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Abstract

In the centrosymmetric binuclear title compound, [Pb-2(N-3)(2)-( NCS)(2)(C12H8N2)(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thiocyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)degrees. The Pb-TT atom is in a Psi-square-antiprismaic coordination.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:54
Last Modified: 31 Jan 2019 04:45
URI: http://eprints.um.edu.my/id/eprint/12413

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