Arman, H.D. and Kaulgud, T. and Tiekink, E.R.T. (2010) 2-Phenylacetic acid-3-{(E)-2-[(E)-pyridin-3-ylmethylidene]hydrazin-1-ylidenemethyl} pyridine (2/1). Acta Crystallographica Section E: Structure Reports Online, 66 (10). O2684-U1577. ISSN 1600-5368,
Full text not available from this repository.Abstract
The asymmetric unit of the title 1:2 adduct, C(12)H(10)N(4)center dot-2C(8)H(8)O(2), comprises a single molecule of 2-phenylacetic acid and half a molecule of 3-pyridinealdazine; the latter is completed by crystallographic inversion symmetry. In the crystal, molecules are connected into a three-component aggregate via O-H center dot center dot center dot N hydrogen bonds. As the carboxyl group lies above the plane through the benzene ring to which it is attached [C-C-C-C = 62.24 (17)degrees] and the 4-pyridinealdazine molecule is almost planar (r.m.s. deviation of the 16 non-H atoms = 0.027 angstrom), the overall shape of the aggregate is that of a flattened extended chair. Layers of these aggregates are connected by C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions and stack parallel to (220).
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 19 Jan 2015 03:42 |
| Last Modified: | 31 Jan 2019 01:08 |
| URI: | http://eprints.um.edu.my/id/eprint/12212 |
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