6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-di ium tris(thiocyanato-kappa N)cuprate(I)

Xu, Na and Niu, Yun-Yin and Ng, S.W. (2010) 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-di ium tris(thiocyanato-kappa N)cuprate(I). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1280-U1042. ISSN 1600-5368,

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Abstract

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-interacting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 angstrom. The Cu(I) atom is displaced by 0.019 (2) angstrom out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 30 Jan 2019 08:30
URI: http://eprints.um.edu.my/id/eprint/12206

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