Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]

Su, M. and Huang, Zhan-Dong and Sun, H. and Yang, G. and Ng, S.W. (2010) Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1220-U493. ISSN 1600-5368,

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Abstract

In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 30 Jan 2019 09:16
URI: http://eprints.um.edu.my/id/eprint/12204

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