Najafi, E. and Amini, M.M. and Ng, S.W. (2010) 8-Hydroxy-2-methylquinolinium dibromido(2-methylquinolin-8-olato-kappa N-2, O)zincate(II) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1276-U1005. ISSN 1600-5368,
Full text not available from this repository.Abstract
The anion of the title salt, (C10H10NO)[ZnBr2(C10H8NO)]center dot-CH3OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hydroxyquinoline ligand. The hydroxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetrahedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methanolic O atom. In the crystal, adjacent ion pairs and solvent molecules are linked by a methanol-halogen O-H center dot center dot center dot Br hydrogen bond, generating a chain running along the a axis.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 19 Jan 2015 03:45 |
| Last Modified: | 31 Jan 2019 05:05 |
| URI: | http://eprints.um.edu.my/id/eprint/12198 |
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