Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1222-U510. ISSN 1600-5368,
Full text not available from this repository.Abstract
The Sn atom in the title polymeric compound, [Sn(C7H7)(3)-(C8H12NO2S2)](n), exists in a trans-C3O2 trigonal-bipyramidal coordination environment in the two independent formula units. The carboxylate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O-covalent bond by 0.093 (4) angstrom and in the second molecule, the Sn atom is displaced by 0.105 (4) angstrom in the same direction.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 19 Jan 2015 03:47 |
| Last Modified: | 31 Jan 2019 04:32 |
| URI: | http://eprints.um.edu.my/id/eprint/12193 |
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