Arman, H.D. and Miller, T. and Tiekink, E.R.T. (2010) catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1212-U419. ISSN 1600-5368, (In Press)
Full text not available from this repository.Abstract
The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 19 Jan 2015 03:47 |
| Last Modified: | 31 Jan 2019 01:10 |
| URI: | http://eprints.um.edu.my/id/eprint/12188 |
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