(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate

Zhang, Kou-Lin and Diao, Guo-Wang and Ng, S.W. (2010) (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1421-U783. ISSN 1600-5368,

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Abstract

The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:06
Last Modified: 30 Jan 2019 08:18
URI: http://eprints.um.edu.my/id/eprint/12001

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