Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis[bis(2methyl-1H-benzimidazole-kappa N-3)(thiocyanato-kappa N)cadmium(II)]

Shaker, S.A. and Khaledi, H. and Ali, H.M. (2010) Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis[bis(2methyl-1H-benzimidazole-kappa N-3)(thiocyanato-kappa N)cadmium(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1464-U1180. ISSN 1600-5368

Full text not available from this repository.

Abstract

The title compound, [Cd-2(NCS)(4)(C8H8N2)(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:06
Last Modified: 29 Jan 2019 09:03
URI: http://eprints.um.edu.my/id/eprint/11998

Actions (login required)

View Item View Item