Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.

Khaledi, H.; Mohd A, H. (2010) Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate. Acta crystallographica. Section E, Structure reports online, 67 (Pt 1). m84. ISSN 1600-5368

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Abstract

In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H⋯O inter-action. In addition, C-H⋯S inter-actions are observed.

Item Type: Article
Creators:
  1. Khaledi, H.
  2. Mohd A, H.
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 05 May 2011 11:40
Last Modified: 05 May 2011 11:40
URI: http://eprints.um.edu.my/id/eprint/1197

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