{2-Morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II).

Suleiman G, N.; Ikmal H, N.A.; Khaledi, H.; Mohd A, H. (2010) {2-Morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II). Acta crystallographica. Section E, Structure reports online, 67 (Pt 1). m58. ISSN 1600-5368

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Abstract

In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N',N''-tridentate Schiff base and the N atoms of two isothio-cyanate ligands in a square-pyramidal geometry. In the crystal, C-H⋯N, C-H⋯O and C-H⋯S inter-actions link adjacent mol-ecules into layers parallel to the ac plane. A weak inter-molecular π-π inter-action occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) Å.

Item Type: Article
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 05 May 2011 11:37
Last Modified: 05 May 2011 11:37
URI: http://eprints.um.edu.my/id/eprint/1195

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