Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).

Ikmal Hisham, Nurul Azimah and Suleiman Gwaram, Nura and Khaledi, Hamid and Ali, Hapipah Mohd (2010) Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m55. ISSN 1600-5368

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Official URL: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC305020...

Abstract

In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.

Item Type: Article
Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 05 May 2011 03:30
Last Modified: 31 Jan 2019 02:29
URI: http://eprints.um.edu.my/id/eprint/1190

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