Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).

Ikmal Hisham, Nurul Azimah; Suleiman Gwaram, Nura; Khaledi, Hamid; Mohd Ali, Hapipah (2010) Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Acta crystallographica. Section E, Structure reports online, 67 (Pt 1). m55. ISSN 1600-5368

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Abstract

In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.

Item Type: Article
Creators:
  1. Ikmal Hisham, Nurul Azimah
  2. Suleiman Gwaram, Nura
  3. Khaledi, Hamid
  4. Mohd Ali, Hapipah
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 05 May 2011 11:30
Last Modified: 05 May 2011 11:30
URI: http://eprints.um.edu.my/id/eprint/1190

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