Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Suleiman G, N.; Ikmal H, N.A.; Khaledi, H.; Mohd A, H. (2010) Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II). Acta crystallographica. Section E, Structure reports online, 67 (Pt 1). m108. ISSN 1600-5368

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Abstract

In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.

Item Type: Article
Creators:
  1. Suleiman G, N.
  2. Ikmal H, N.A.
  3. Khaledi, H.
  4. Mohd A, H.
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Additional Information: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 05 May 2011 11:21
Last Modified: 05 May 2011 11:21
URI: http://eprints.um.edu.my/id/eprint/1184

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