(4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate

Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (12). M1558-U726. ISSN 1600-5368,

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Abstract

The V-V atom in the title compound, [V(C7H6ClN2O)(C16H11ClN2O3)O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazinylidene) propionate dianion. The distorted octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds about a center of inversion, generating a dimer.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 08 Jan 2015 01:57
Last Modified: 30 Jan 2019 08:26
URI: http://eprints.um.edu.my/id/eprint/11694

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